MSDS-ACROLEIN DIETHYL ACETAL

- Jul 22, 2019-

SAFETY DATA SHEET

1.IDENTIFICATION   OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER


Product name

Acrolein   Acetal


Product code

XA-008036


Company:

Hubei   Xinjing New Material Co., Ltd.


Address:

Room 404 Block 7 B Huifeng Business   Park, Gutian 2ND Road, Qiaokou District,Wuhan China.


Responsible Department:

Sales   Department


Telephone:

027-83838590


Fax:

027-83496451  


e-mail:

caroline@xinjingchem.com  


Version

2




               

 2.HAZARDS   IDENTIFICATION

Classification of the GHS


PHYSICAL HAZARDS



Flammable liquids                                     

Category   2


HEALTH HAZARDS

Acute   toxicity (Oral)

Eye   irritation

Skin   corrosion/irritation   

 

Category   5

Category   2A

Category   2


ENVIRONMENTAL HAZARDS

Not   classified

GHS label elements


Pictograms or hazard symbols  

                     


Signal word

Danger


Hazard statement

H225: Highly flammable liquid and vapour

H315   Causes skin irritation.

H319:Causes serious eye irritation.


Precautionary statements



[Prevention]

P210:   Keep away from heat/sparks/open   flames/hot surfaces. - No smoking.

P233:   Keep container tightly closed.

P241+P243Use explosion-proof   electrical/ventilating/lighting equipment. Take precautionary measures against ignition by   the static discharge and the spark.

P280Wear protective   gloves/eyeprotection/face protection.



[Response]

P305+P351+P338: IF IN EYES: Rinse   cautiously with water for several minutes. Remove contact lenses, if present and   easy to do. Continue rinsing.



[Storage]    

P403+P235:Store in a well-ventilated   place. Keep cool.



[Disposal]

P501Dispose of contents/container   through a waste management company authorized by the local government.



Other hazards which do not   result in classification  none







     

3.COMPOSITION/INFORMATION   ON INGREDIENTS


Substance/mixture

Substance


Compontent(s)

Acrolein Acetal


Chemical Formula

C7H14O2


Formula weight:

130.19g/mol


CAS

3054-95-3


EC

221-276-0


Percent

>98.0%(GC)  


Synonyms:

3,3-Diethoxy-1-propene

   

 4.FIRST AID MEASURES


Inhalation:

Remove victim to fresh air and   keep at rest in a position comfortable for breathing.

Call a POISON CENTER or   doctor/physician if you feel unwell.


Skin contact:

 

Remove/Take off immediately all   contaminated clothing. Gently wash with plenty of soap and water. If skin   irritation or rash occurs: Get medical advice/attention.


Eye contact:

 

Rinse cautiously with water for   several minutes. Remove contact lenses, if present and easy to do. Continue   rinsing. If eye irritation persists: Get medical advice/attention.


Ingestion:

 

Call a POISON CENTER or   doctor/physician if you feel unwell. Rinse mouth.


Protection of first-aiders:

A rescuer should wear personal   protective equipment, such as rubber gloves and airtight goggles.

5.FIRE-FIGHTING   MEASURES


Suitable extinguishing

media:

Dry   chemical, foam, carbon dioxide.

 


Unsuitable extinguishing

media:

Water   (It may scatter and spread fire.)


Specific   hazards arising  from the chemical:

This substance may polimerize   explosively when heated or involved in a fire.

Container may explode when   heated. Combatfire from a sheltered position


Precautions for firefighters:

Fire-extinguishing   work is done from the windward and the suitable fire-extinguishing method   according to the surrounding situation is used. Uninvolved persons should   evacuate to a safe place. In case of firein the surroundings: Keep containers   cool by spraying with water. Eliminate all ignition sources if safe to do so.  


Special protective

equipment for firefighters:

When extinguishing   fire, be sure to wear personal protective equipment.

 

 

6.ACCIDENTAL   RELEASE MEASURES


Personal precautions,

protective equipment and

emergency procedures:

Use personal protective   equipment. Keep people away from and upwind of spill/leak.

Ensure adequate ventilation.   Entry to non-involved personnel should be controlled around the leakage area   by roping off, etc.


Environmental precautions:

Prevent product from entering   drains.

 


Methods and materials for

containment and cleaning

up:

 

Absorb spilled material in dry   sand or inert absorbent before recovering it into an airtight container. In   case of large amount of spillage, contain a spill by bunding.

Adhered or collected material   should be promptly disposed of, in accordance with appropriate laws and   regulations


Prevention of secondary

hazards:

Remove all sources of ignition.   Fire-extinguishing devices should be prepared in case of a fire. Use   spark-proof tools and explosion-proof equipment.

 

7.HANDLING   AND STORAGE

Precautions for safe handling


Technical measures

Handling is performed in a well   ventilated place. Wear suitable protective equipment.

Prevent generation of vapour or   mist. Keep away from heat/sparks/open flame/hot surfaces. -No smoking. Take   measures toprevent the build up of electrostatic charge. Use explosion-proof   equipment. Wash hands and face thoroughly after handling.

Use a closed system if   possible. Use a ventilation, local exhaust if vapour or aerosol will be   generated.


Advice on safe handling:

Avoid contact with skin, eyes   and clothing.

Confirm in advance if peroxides   exist when operations involving heating such as distillation are carried out.  

Conditions   for safe storage, including any incompatibilities


Storage conditions:

Keep container tightly closed.   Store in an explosion-poof refregerator.

Store under inert gas.

Store away from incompatible   materials such as oxidizing agents.

Heat-sensitive,   Light-sensitive, Air-sensitive


Packaging material

Comply with laws.

 

 

 

8.EXPOSURE   CONTROLS / PERSONAL PROTECTION


Engineering   controls:

Install a closed system or   local exhaust. Also install safety shower and eye bath.


Personal   protective equipment




Respiratory   protection:

Vapor respirator. Follow local   and national regulations.

 



Hand   protection:

Protective gloves.



Eye   protection:

Safety glasses. A face-shield,   if the situation requires.



Skin   and body protection:

Protective clothing. Protective   boots, if the situation requires.

 

 

 

9.PHYSICAL   AND CHEMICAL PROPERTIES


Physical   state (20°C):

Liquid


Form:

clear


Color:

Colorless   - Slightly pale yellow


Odor:

No data   available


pH:

No data   available


Melting   point/freezing point:

No data   available


Boiling   Point/Range

124-125


Flash   Point:

15


Explosive   limits




Lower:

No data   available



Upper:

No data   available


Density:

0.852 g/mL @ 25


Solubility:

[Water]   Very slightly soluble

[Other   solvents]    Soluble:  Ether, Alcohols,


Vapour   density:

No data   available


Vapour   pressure:

No data   available

 

10.STABILITY   AND REACTIVITY


Chemical   stability:

Polymerization may occur under   the influences of heat, light or on contact with polymelization initiators   such as peroxides etc.

May form explosive peroxides.


Possibility   of hazardous  reactions

No special reactivity has been   reported.


Conditions   to avoid:

Heat, Spark, Open flame, Static   discharge, Air, Light


Incompatible   materials:

Oxidizing agents, Acids


Hazardous   Decomposition

Products:

Carbon monoxide, Carbon dioxide

 

 

 

 

11.TOXICOLOGICAL   INFORMATION


Acute   Toxicity:

No data   available


Skin   corrosion/irritation:

No data   available


Serious   eye damage/irritation:

No data   available


Germ   cell mutagenicity

mmo-sat   5 ug/plate


Carcinogenicity:

IARC = No data available



NTP = No data available


Reproductive   toxicity:

No data   available


RTECS   Number:

AS1370000

 

 12.ECOLOGICAL INFORMATION


Ecotoxicity:




Fish:

No data   available



Crustacea:  

No data   available



Algae:

No data   available


Persistence   / degradability:

No data   available


Bioaccumulative

potential(BCF):

No data   available


Mobillity   in soil




log   Pow:

1811



Soil   adsorption (Koc):

No data   available



Henry's   Law

constant(PaM3/mol):

No data   available






 

13.DISPOSAL   CONSIDERATIONS


Recycle to process, if   possible. Consult your local regional authorities. You may be able to burn in   a chemical incinerator equipped with an   afterburner and scrubber system but exert extra care in igniting as this   material is highly flammable. Observe all   federal, state and local regulations when disposing of the substance

 

14.TRANSPORT   INFORMATION


Hazards   Class:

3:   Flammable liquid.


UN-No:

2374


Proper   shipping name:

3,3-DIETHOXYPROPENE


Packing   group:

II

 15.REGULATORY INFORMATION


Safe management ordinance of   dangerous chemical product (State Council announces on January 26, 2002 and   revised on February 16,2011): Safe use and production, the storage of a   dangerous chemical, transport, loading and unloading were prescribed.

 

16. OTHER   INFORMATION


  This     MSDS was prepared sincerely on the basis of the information we could     obtained, however, any warranty shall not be given regarding the data contained and the assessment of hazards and toxicity.     Prior to use, please investigate not only the hazards and toxicity     information but also the laws and regulations of the     organization, area and country where the products are to be used, which     shall be given the first priority.products are supposed to be used promptly after purchase in consideration of     safety. Some new information or amendments may be added afterwards. If the     products are to be used far behind the expected     time of use or you have any questions, please feel free to contact us. The     stated cautions are for normal handling only. In case     of special handling, sufficient care should be taken, in addition to the     safety measures suitable for the situation. All chemical products should be treated with the recognition of "having unknown     hazards and toxicity", which differ greatly depending on the     conditions and handling when in use and/or the     conditions and duration of storage. The products must be handled only by     those who are familiar with specialized knowledge and have experience or under the guidance of those specialists throughout     use from opening to storage and disposal. Safe usage conditions shall be     set up on each user's own responsibility.